Journal
ORGANIC LETTERS
Volume 14, Issue 13, Pages 3296-3299Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol3012666
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Funding
- Indian Institute of Science, Bangalore
- DST, New Delhi [SR/FT/CS-90/2010]
- CSIR, New Delhi [01(2505)/11/EMR-II]
- CSIR
- IISc
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Michael additions of alpha-substituted nitrophosphonates to various nitroolefins are shown to proceed with high diastereo- and enantioselectivity when catalyzed by a quinine-derived thiourea-tertiary amine bifunctional catalyst and generate alpha,gamma-diaminophosphonic acid precursors with contiguous quaternary and tertiary stereocenters.
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