Journal
ORGANIC LETTERS
Volume 14, Issue 14, Pages 3628-3631Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol301420t
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Funding
- Czech Science Foundation [P207/12/2027]
- Ministry of Education, Youth and Sports of the CR [MSM0021620857]
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Electrophilic aromatic substitution in the calix[n]arene series is a well-established procedure leading exclusively to para-substituted derivatives. An unprecedented regioselectivity of the mercuration reaction leading to the meta-substituted calix[4]arenes is described. These compounds represent a new type of substitution pattern in classical calixarene chemistry and open the door for the straightforward synthesis of inherently chiral receptors based on calixarenes.
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