Journal
ORGANIC LETTERS
Volume 14, Issue 20, Pages 5322-5325Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol302506f
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Funding
- National Science Foundation
- National Institutes of Health [CHE-1012578, NIBIB EB008484]
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A series of sterically shielded pyrrolidine nitroxides were synthesized, and their reduction by ascorbate (vitamin C) indicate that nitroxide 3, a tetraethyl derivative of 3-carboxy-PROXYL, is reduced at the slowest rate among known nitroxides, i.e., at a 60-fold slower rate than that for 3-carboxy-PROXYL.
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