4.8 Article

Dual-Mode Control of PET Process in a Ferrocene-Functionalized [2]Rotaxane with High-Contrast Fluorescence Output

Journal

ORGANIC LETTERS
Volume 14, Issue 9, Pages 2334-2337

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/ol300753d

Keywords

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Funding

  1. NSFC/China [20902024, 21190033]
  2. National Basic Research 973 Program [2011CB808400]
  3. Foundation for the Author of National Excellent Doctoral Dissertation of China [200957]
  4. Shanghai Pujiang Talent Program [10PJ1402700]
  5. Fok Ying Tong Education Foundation [121069]
  6. SRFDP [20090074120017]
  7. Shanghai Chenguang project [09CG26]
  8. Fundamental Research Funds for the Central Universities [WJ1014001]

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The shuttling motion of the ferrocene-functionalized macrocycle between the dibenzylammonium and the N-methyltriazolium recognition sites in a bistable [2]rotaxane, as well as the photoinduced electron transfer process occurring between ferrocene units and the morpholin-naphthalimide fluorescent stopper, can be adjusted not only by acid-base stimuli but also addition-removal of the fluoride anion, along with remarkable, high-contrast fluorescent intensity changes.

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