4.8 Article

(+)-Camphor Derivative Induced Asymmetric [2+2] Photoaddition Reaction

Journal

ORGANIC LETTERS
Volume 14, Issue 3, Pages 776-779

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/ol203314y

Keywords

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Funding

  1. China NSFC [20802013, 21002018, 2107-2038]
  2. Fundamental Research Funds for the Central Universities [HIT.BRET2.2010001]
  3. WZSTP [G20100056]
  4. ZJSTP [2011C23116]

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An efficient approach to construct an enantiomerically pure cyclobutane skeleton by means of the chiral auxiliary induced [2 + 2] photoaddition reactions has been described. This asymmetric photoreaction exhibited high diastereoselectivity and provided the photoadducts in excellent yields.

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