Journal
ORGANIC LETTERS
Volume 14, Issue 16, Pages 4190-4193Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol301854z
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Funding
- Research Grants Council of Hong Kong [GRF402508]
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Novel silylethynylated N-heteropentacenes that have three adjacent pyrazine rings at the center of a pentacene backbone are reported. These hexaazapentacenes exhibit a record low energy level of lowest unoccupied molecular orbital (LUMO) for N-heteropentacenes and thus are able to oxidize dihydroanthracene to anthracene. Their synthetic precursors are the corresponding dihydrohexaazapentacenes, which exhibit interesting H-bonding.
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