4.8 Article

Versatile 2,7-Substituted Pyrene Synthons for the Synthesis of Pyrene-Fused Azaacenes

Journal

ORGANIC LETTERS
Volume 14, Issue 16, Pages 4170-4173

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/ol301841h

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Funding

  1. Freiburg Institute for Advanced Studies
  2. Deutsche Forschungsgemeinschaft [AU 373/3-1, MA 5215/4-1]
  3. POLYMAT (Basque Excellence Research Center)
  4. Basque Science Foundation for Science (Ikerbasque)

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A new synthetic route to prepare a series of versatile 2,7-substituted pyrene synthons for the synthesis of pyrene-fused azaacenes is described. By using such synthons, a library of eight pyrene-fused azacenes with different electronic structures and in most cases with enhanced solubility has been synthesized and characterized.

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