Journal
ORGANIC LETTERS
Volume 14, Issue 8, Pages 2188-2190Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol300582y
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Funding
- Laboratory for Catalysis and Sustainable Chemistry (LSK) at Paul Scherrer Institute, Villigen, Switzerland
- ETH Zurich, Switzerland
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Cross-coupling between diphenylphosphine oxide and halogenated benzoic acids catalyzed by Pd/C in water is a green, simple, and fast protocol to obtain water-soluble tertiary phosphine oxides without the addition of ligands and additives. Low reaction times and microwave irradiation make this method general and excellent for laboratory and large-scale synthesis without the need to use organic solvents in reactions and workup.
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