Journal
ORGANIC LETTERS
Volume 14, Issue 11, Pages 2726-2729Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol3009446
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Funding
- National Natural Science Foundation of China [21021001, 21172151]
- National Basic Research Program of China (973 Program) [2010CB833300]
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Catalytic asymmetric sulfenylation of unprotected 3-substituted oxindoles has been developed via cooperative catalysis of a chiral N,N-dioxide-Sc(OTf)(3) complex and a Bronsted base. Utilizing readily available N-(phenylthio)phthalimide as the sulfur source, a wide range of optically active 3-phenylthiooxindoles were obtained in excellent yields with excellent enantioselectivities under mild reaction conditions.
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