Journal
ORGANIC LETTERS
Volume 14, Issue 12, Pages 3154-3157Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol301248d
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Funding
- National Natural Science Foundation of China [21072194, 21172222]
- 973 program [2010-CB833300]
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A simple chiral sulfur alkene hybrid ligand has proven to be highly effective for rhodium-catalyzed formal cycloaddition reactions of racemic butadiene monoxide and imines to furnish spirooxindole oxazolidines or 1,3-oxazolidines with high yields and stereoselectivities. A possible dynamic kinetic resolution as well as a kinetic resolution is considered to be involved in this catalytic process.
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