Journal
ORGANIC LETTERS
Volume 14, Issue 9, Pages 2414-2417Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol300853z
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Funding
- Ministry of Education, Culture, Sports, Science and Technology in Japan
- Chiba University
- Eisai Award in Synthetic Organic Chemistry, Japan
- Grants-in-Aid for Scientific Research [24750033] Funding Source: KAKEN
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A direct benzylic oxidation of alkylarenes via C-H bond abstraction was developed using alkali metal bromides and oxidants under mild conditions. This reaction proceeded with excellent selectivity by thermal oxidation or photooxidation to provide a broad range of carbonyl compounds containing electron-deficient aryl carbonyl compounds in high yields.
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