Journal
ORGANIC LETTERS
Volume 14, Issue 24, Pages 6130-6133Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol302669q
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Funding
- Japan Society of the Promotion of Science (JSPS) [16201045, 19201045]
- Grants-in-Aid for Scientific Research [21310145] Funding Source: KAKEN
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The Prins cyclization of hydroxy or amino group-containing allenylsilanes with carbonyl compounds occurred at the allenic terminus in a regio- and stereoselective manner to give the di- or trisubstituted tetrahydrofurans, tetrahydropyrans, and pyrrolidines. During the reaction, the allenic axial chirality of the starting material was efficiently transferred to the newly formed carbon chiral centers of the product.
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