Journal
ORGANIC LETTERS
Volume 14, Issue 8, Pages 2038-2041Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol300489q
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Funding
- Fundamental Research Funds for the Central Universities
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A bulky group was introduced by design into a diamine catalyst, and a series of robust and tunable bulky chiral primary amine catalysts were developed and successfully applied in the direct conjugate addition of substituted rhodanines to alpha,beta-unsaturated ketones. High yields (up to 99%) and excellent diastereoselectivities (up to 99:1 dr) and enantioselectivities (up to 98% ee) were observed.
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