Journal
ORGANIC LETTERS
Volume 14, Issue 23, Pages 6024-6027Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol3028972
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Funding
- National Health Research Institutes
- National Science Council of Taiwan [NSC-100-2113-M-400-002, NSC-101-2113-M-400-003-MY2]
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The radical cascade protocol of the alpha-cyano alpha-TMS/aryl-capped alkynyl aryl ketones promoted by tert-butyl hydroperoxide under catalysis with tetrabutylammonium iodide in refluxing benzene has been developed, leading to the construction of a variety of highly functionalized [6,6,5] tricyclic frameworks in an efficient manner.
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