Journal
ORGANIC LETTERS
Volume 14, Issue 20, Pages 5262-5265Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol302423b
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Funding
- Program for Changjiang Scholars and Innovative Research Team in University [IRT0965]
- Joint Fund of NSFC-Guangdong Province [U0932004]
- National Natural Science Foundation of China [81172946]
- Research Team Program of Natural Science Foundation of Guangdong Province [8351063201000003]
- Program for New Century Excellent Talents in University [NCET-11-0857]
- Science and Technology Planning Project of Guangzhou [2011J2200046, 2011J2200045]
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The first monoterpene-based meroterpenoid (1) and two novel sesquiterpene-based ones (2 and 3) with unprecedented skeletons were isolated from the leaves of Psidium guajava. Their structures with absolute configuration were elucidated by extensive spectroscopic studies. A plausible biosynthetic pathway for all meroterpenoids from the title plant is also proposed. Compounds 2 and 3 showed significant cytotoxicity toward HepG2 and HepG2/ADM cells.
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