4.8 Article

One-Pot Synthesis of Pyranocoumarins via Microwave-Assisted Pseudo Multicomponent Reactions and Their Molecular Switching Properties

Journal

ORGANIC LETTERS
Volume 14, Issue 5, Pages 1190-1193

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/ol203229z

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Funding

  1. National Science Council of Taiwan [NSC 98-2113-M-029-003-MY2]

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Two new pyranocoumarins were synthesized via one-pot, microwave-assisted pseudo multicomponent condensations of coumarin and 4-methylquinoline to investigate their molecular switching properties. Both are light-sensitive and have a distinct change of color upon UV irradiation. The reaction can be reverted by treating the photogenerated products with imidazoline-functionalized magnetic nanoparticles, which can be swiftly recycled with an external permanent magnet.

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