Journal
ORGANIC LETTERS
Volume 14, Issue 3, Pages 792-795Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol203329u
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Funding
- Bayer-Schering Pharma AG
- Bayer Services GmbH
- BASF AG
- Sasol GmbH
- Evonik Industries
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Ligand exchange acetalization of acetals in the presence of catalytic amounts of mandelic acid and titanium tert-butoxide is reported. This transformation is successfully extended to glycosylation of unprotected and unactivated pentoses. Even unreactive pentoses such as D-arabinose or D-lyxose can be transformed by this new methodology into corresponding isopropyl glycosides.
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