Journal
ORGANIC LETTERS
Volume 14, Issue 8, Pages 2026-2029Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol300534j
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Funding
- NSF [0911017]
- Direct For Mathematical & Physical Scien
- Division Of Chemistry [0911017] Funding Source: National Science Foundation
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An easy and expeditious route to substituted piperidines is described. A Ni-phosphine complex was used as catalyst for [4 + 2] cycloaddition of 3-azetidinone and alkynes. The reaction has broad substrate scope and affords piperidines in excellent yields and excellent regioselectivity. In the reaction of an enantiopure azetidinone, complete retention of stereochemistry was observed.
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