4.8 Article

Helicity Control of an Indolocarbazole Foldamer by Chiral Organic Anions

Journal

ORGANIC LETTERS
Volume 14, Issue 19, Pages 5018-5021

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/ol3022148

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Funding

  1. National Research Foundation of Korea (NRF)
  2. Korea government (MEST) [2011-0017945]
  3. Korea Research Institute of Chemical Technology (KRICT) [TSII3-02]
  4. Ministry of Knowledge Economy (MKE), Republic of Korea
  5. Ministry of Education and Human Resources Development

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Chiral organic anions such as camphorsulfonates and cAMP give rise to the preferential formation of a one-handed helix of an indolocarbazole foldamer, thus inducing characteristic circular dichroic (CD) signals. Moreover, the on and off switching of the chiroptical signal can be operated by acid and base chemistry which efficiently controls the association and dissipation of the foldamer and cAMP.

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