Journal
ORGANIC LETTERS
Volume 14, Issue 17, Pages 4430-4433Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol301938z
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Funding
- National Science Foundation [CHE0910597]
- National Institutes of Health [NIGMS P50GM067082]
- Division Of Chemistry
- Direct For Mathematical & Physical Scien [0910597] Funding Source: National Science Foundation
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Functionalized naphthalenes are valuable building blocks in many important areas. A microwave-assisted, intramolecular dehydrogenative Diels-Alder reaction of styrenyl derivatives to provide cyclopenta[b]naphthalene substructures not previously accessible using existing synthetic methods is described. The synthetic utility of these uniquely functionalized naphthalenes was demonstrated by a single-step conversion of one of these cycloadducts to a fluorophore bearing a structural resemblance to Prodan.
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