Journal
ORGANIC LETTERS
Volume 14, Issue 6, Pages 1508-1511Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol3002392
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Funding
- Chinese Academy of Sciences
- National Natural Science Foundation of China [21102028]
- Suzhou Jiahong Optoelectronics
- Ministry of Science and Technology of China
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A series of mono- and bisadducts of thieno-o-quinodimethane with C-60 (TOQC) was efficiently prepared through the Diels-Alder reaction of pristine or solubilizing side-chain-substituted 2,3-bis(chloromethyl)thiophene with C-60. The pristine TOQC bisadduct (bis-TOQC) shows much higher performance than the side-chain-substituted TOQC bisadducts in polymer solar cells, while the situation is inverse for the TOQC monoadducts. The best power conversion efficiency of 5.1% was achieved from the bis-TOQC:P3HT solar cells under simulated AM1.5G irradiation (86 mW/cm(2)).
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