Journal
ORGANIC LETTERS
Volume 14, Issue 17, Pages 4502-4505Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol3019902
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Funding
- MEXT, Japan
- New Energy and Industrial Technology Development Organization (NEDO)
- Grants-in-Aid for Scientific Research [22550093] Funding Source: KAKEN
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An asymmetric allylic substitution of simple allylic ethers with arylboronic acids in the presence of a rhodium(I)/(R)-DTBM-SEGPHOS catalyst has been developed. The reactions proceeded smoothly at room temperature to give the corresponding branch products with excellent regioselectivities and good to excellent enantioselectivities.
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