Journal
ORGANIC LETTERS
Volume 14, Issue 11, Pages 2894-2897Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol301175z
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- Hangzhou Normal University
- MOE in Singapore (ARC) [T206B3225]
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A chiral N-heterocyclic carbene (NHC)-catalyzed Diels-Alder reaction of 2-oxoindolin-3-ylidenes and alpha-chloroaldehydes was developed for the synthesis of fused pyrano[2,3-b]indoles in good to excellent yields (up to 99%) with high cis-diastereoselectivities (>99:1 dr) and enantioselectivities (up to >99% ee).
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