4.8 Article

Selective and Effective Binding of Pillar[5,6]arenes toward Secondary Ammonium Salts with a Weakly Coordinating Counteranion

Journal

ORGANIC LETTERS
Volume 14, Issue 16, Pages 4126-4129

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/ol301757q

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Funding

  1. National Natural Science Foundation of China [20902057, 21002061, 21142012, 21101031]
  2. Leading Academic Discipline Project of Shanghai Municipal Education Commission [J50101]
  3. State Key Laboratory of Molecular Engineering of Polymers (Fudan University)

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The selective and effective binding of secondary ammoniums with a weakly coordinating tetrakis[3,5-bis(trifluoromethyl)phenyl]borate (BArF) counteranion by per-ethylated pillar[5,6]arenes is reported. The construction of a first pillararene-based self-sorting system consisting of two wheels and two axles is also described.

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