Journal
ORGANIC LETTERS
Volume 14, Issue 16, Pages 4178-4181Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol301846q
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Funding
- National Science Foundation [CHE-0848560]
- SUNY Buffalo Chemistry Department
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A relay strategy was employed to achieve an intermolecular ene-yne metathesis between 1,1-disubstituted alkenes and alkynes. The relay serves to activate an unreactive alkene which will not participate in ene-yne metathesis. The new relay cross ene-yne metathesis gives rise to 1,1,3-trisubstituted-1,3-dienes previously inaccessible by direct ene-yne metathesis methods.
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