Journal
ORGANIC LETTERS
Volume 14, Issue 4, Pages 976-979Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol203109a
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Funding
- NSFC [20802074]
- 973 Program [2010C-B833300]
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The catalytic enantioselective three-component Petasis reaction among salicylaldehydes, amines, and organoboronic acids with a newly designed thiourea-binol catalyst is presented. A broad range of alkylaminophenols can be obtained in good yield (up to 92%) and good to high enantioselectivity (up to 95% ee). A possible reaction pathway for this catalytic enantioselective Petasis reaction is tentatively proposed.
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