Journal
ORGANIC LETTERS
Volume 14, Issue 17, Pages 4548-4551Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol302132s
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- Deutsche Forschungsgemeinschaft [DFG Sp 498/2-1]
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The Heck protocol was applied for the first time to the atroposelective synthesis of macrocyclic natural products. As ring closure to bis(bibenzyls) of the isoplagiochin type leads to a configurationally stable biaryl axis in the molecule, cyclization could be conducted atroposelectively in the presence of a chiral BINAP ligand.
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