Journal
ORGANIC LETTERS
Volume 14, Issue 16, Pages 4062-4065Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol301626u
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- Japan Regional Innovation Strategy Program by the Excellence (creating international research hub for advanced organic electronics) of Japan Science and Technology Agency (JST)
- Ministry of Education, Culture, Sports, Science and Technology, Japan
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Isomerically pure syn-/anti-isomers of 2,8-dimethylanthradithiophene (DMADT) were synthesized in five steps and characterized using thermogravimetry, X-ray single crystal analysis, UV-vis absorption, and electrochemical measurements. The physical properties in solution were slightly different for each isomer, whereby the more obvious differences were observed in the solid state. A field-effect transistor using the anti-isomer showed a much higher performance than that using the syn-isomer.
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