Journal
ORGANIC LETTERS
Volume 14, Issue 17, Pages 4518-4521Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol302005f
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A series of new thiourea catalysts prepared from natural amino acids have been applied in organocatalytic asymmetric Michael additions of alpha-nitrocyclohexanone to nitroalkenes. The resulting addition products are formed with excellent enantioselectivities (up to an er of 98:2) in good yields (up to 90%).
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