Journal
ORGANIC LETTERS
Volume 14, Issue 18, Pages 4842-4845Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol302168q
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Funding
- Japan Private School Promotion Foundation
- MEXT
- CCIS
- Grants-in-Aid for Scientific Research [24590025] Funding Source: KAKEN
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The combination of 1,1,3,3-tetramethyldisiloxane (TMDS) and trimethylbromosilane (Me3SiBr) with a catalytic amount of indium bromide (InBr3) undertook direct bromination of carboxylic acids, which produced the corresponding alkyl bromides in good to excellent yields. The reducing system was tolerant to several functional groups.
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