4.8 Article

1,1-Carboboration Route to Substituted Naphthalenes

Journal

ORGANIC LETTERS
Volume 14, Issue 6, Pages 1448-1451

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/ol300193e

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Funding

  1. Deutsche Forschungsgemeinschaft

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1,2-Bis(alkynyl)benzene derivatives react with strongly electrophilic boranes to yield in boryl-functionalized bulky naphthalene derivatives by means of a sequence of 1,1-carboboration reactions. These substrates can be functionalized by transition metal catalyzed cross-coupling reactions.

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