Journal
ORGANIC LETTERS
Volume 14, Issue 3, Pages 828-831Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol203355g
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- National Cancer Institute of the United States National Institutes of Health [CA-76497]
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The spirotetronate okilactomycin D (7) has been efficiently synthesized by a route featuring a substrate-controlled, diastereoselective (8:1) intramolecular Diels-Alder (IMDA) reaction of 11. The assigned absolute configuration of (-)-7 was confirmed.
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