Journal
ORGANIC LETTERS
Volume 14, Issue 3, Pages 855-857Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol2033724
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Funding
- GCOE
- WPI Initiative from JSPS
- Japan Science Technology Agency
- Asahi Glass Foundation
- [21229001]
- [22689001]
- Grants-in-Aid for Scientific Research [21229001, 22689001] Funding Source: KAKEN
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A rhodium complex catalyzed the reaction of aryl methyl ethers and thioesters giving the corresponding aryl esters and methyl sulfides. S-(p-Chlorophenyl) p-(dimethylamino)benzothioate was used for the reaction of methyl aryl ethers with electron-withdrawing groups, and an S-(p-tolyl) derivative was used for those with electron-donating groups. Polymethoxybenzenes were converted to the esters in a regioselective manner.
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