Journal
ORGANIC LETTERS
Volume 14, Issue 23, Pages 6016-6019Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol302908a
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Funding
- Uehara Memorial Foundation
- Ministry of Education, Culture, Sports, Science and Technology, Japan [12045232]
- Grants-in-Aid for Scientific Research [24105530, 23390007] Funding Source: KAKEN
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Asymmetric bromolactonization of prochiral cyclohexadiene derivatives with N-bromosuccimide proceeded in the presence of (DHQD)(2)PHAL as a chiral catalyst to afford the corresponding bromolactones with up to 93% ee. This reaction was also applicable to the kinetic resolution of a racemic cyclic ene-carboxylic acid, where the starting material was recovered with high enantioselectivity.
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