4.8 Article

A Non-Photochemical Approach to the Bicyclo[3.2.0]heptane Core of Bielschowskysin

Journal

ORGANIC LETTERS
Volume 14, Issue 9, Pages 2195-2197

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/ol3006419

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Funding

  1. University of Vienna [IK I041-N]
  2. Austrian Science Fund (FWF) [P22180]
  3. Austrian Science Fund (FWF) [P 22180] Funding Source: researchfish
  4. Austrian Science Fund (FWF) [P22180] Funding Source: Austrian Science Fund (FWF)

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An asymmetric synthesis of the tricyclic core (-)-1 of the marine diterpene bielschowskysin is described. In particular, a methodology was developed to introduce the crucial quaternary center at C-12.

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