Journal
ORGANIC LETTERS
Volume 14, Issue 19, Pages 5122-5125Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol302392k
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Funding
- CNRS
- University Joseph Fourier
- ANR [Lycomet ANR-11-JS-07-006-01]
- Ministere de la Recherche
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The addition of lithiated ynol ethers to chiral N-sulfinyl imines proceeds in high yield and diastereoselectivity. The selectivity is completely reversed by the addition of boron trifluoride. These alkoxypropargyl sulfinamides can be reduced to afford enol ethers, selectively oxidized to busyl derivatives, or the ynol ether can be hydrolyzed to afford beta-amino esters.
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