4.8 Article

Selective Synthesis and Crystal Structure of [10]Cycloparaphenylene

Journal

ORGANIC LETTERS
Volume 14, Issue 13, Pages 3284-3287

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/ol301242t

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Funding

  1. Core Research for Evolution Science and Technology (CREST), Japan Science and Technology Agency
  2. Grants-in-Aid for Scientific Research [24750087] Funding Source: KAKEN

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[10]Cycloparaphenylene ([10]CPP) was selectively synthesized in four steps in 13% overall yield from commercially available 4,4'-diiodobiphenyl by using mono-I-Sn exchange, Sn-Pt transmetalation, I-Pd exchange, and subsequent oxidative coupling reactions. The single-crystal X-ray structure of [10]CPP is described.

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