Journal
ORGANIC LETTERS
Volume 14, Issue 8, Pages 2180-2183Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol300754n
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- Deutsche Forschungsgemeinschaft
- Bayer Pharma AG
- Chemtura Organometallics GmbH Bergkamen
- Bayer Services GmbH
- BASF AG
- Sasol GmbH
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Isoleucine-catalyzed direct enantioselective aldol additions between enolizable aldehydes are reported. Intermediate acetal structures dictate the configurative outcome and were supported by a hydrogen bond. This direct isoleucine-catalyzed aldol addition represents a welcome complement to both proline- and histidine-catalyzed aldol additions of enolizable aldehydes.
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