Journal
ORGANIC LETTERS
Volume 14, Issue 6, Pages 1398-1401Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol300111m
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Funding
- HKUST
- Hong Kong RGC [SBI11SC02, DAG11SC01]
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An efficient N-heterocyclic carbene (NHC)-catalyzed internal redox reaction of alkynals that bear a y leaving group has been developed. This process provides a new access to a range of allenoates in good yields. Preliminary results demonstrate that the enantioselective variant can also be achieved.
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