Journal
ORGANIC LETTERS
Volume 14, Issue 15, Pages 3890-3893Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol301620z
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Funding
- National Science Foundation of China [21032003, 20921092]
- National Basic Research Program of China [2010CB833300]
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Highly enantioselective Ir-catalyzed hydrogenation of seven-membered cyclic imines of benzodiazepinones and benzodiazepines was achieved with up to 96% ee. This method provides a direct access to synthesize a range of chiral cyclic amines existing in numerous important natural products and clinical drugs.
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