4.8 Article

Modulating the Photoisomerization of N,C-Chelate Organoboranes with Triplet Acceptors

Journal

ORGANIC LETTERS
Volume 14, Issue 21, Pages 5610-5613

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/ol302742g

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Funding

  1. Natural Sciences and Engineering Research Council of Canada
  2. Japan Society for the Promotion of Science
  3. Grants-in-Aid for Scientific Research [24109007] Funding Source: KAKEN

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Triplet acceptors such as naphthalene, pyrene, and anthracene have been found to be highly effective in controlling the photoisomerization efficiency of N,C-chelate boryl chromophores, establishing the involvement of a photoactive triplet state in the isomerization of this class of photochromic compounds.

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