Journal
ORGANIC LETTERS
Volume 14, Issue 3, Pages 800-803Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol203331r
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Funding
- National Institutes of Health [GM 46503]
- National Science Foundation [CHE-0748121]
- Division Of Chemistry
- Direct For Mathematical & Physical Scien [0748121] Funding Source: National Science Foundation
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Silyl-protected enol diazoacetates undergo dirhodium(II)-catalyzed reactions with nitrile oxides to form acid-labile ketenimines via dipolar cycloaddition of nitrile oxides to a donor/acceptor cyclopropene and Lossen rearrangement of the dipolar adduct; acid catalysis converts the ketenimine to the furan product.
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