Journal
ORGANIC LETTERS
Volume 14, Issue 16, Pages 4182-4185Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol301847m
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Funding
- Boehringer Ingelheim
- DuPont
- Eli Lilly
- Amgen
- AstraZeneca
- Roche
- A. P. Sloan Foundation
- Foote family (fellowship)
- University of California, Los Angeles
- NSF [CHE-1048804]
- National Center for Research Resources [S10RR025631]
- Direct For Mathematical & Physical Scien [1048804] Funding Source: National Science Foundation
- Division Of Chemistry [1048804] Funding Source: National Science Foundation
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A facile nickel-catalyzed method to achieve the amination of synthetically useful aryl sulfamates and carbamates is reported. Contrary to most Ni-catalyzed amination reactions, this user-friendly approach relies on an air-stable Ni(II) precatalyst, which, when employed with a mild reducing agent, efficiently delivers aminated products in good to excellent yields. The scope of the method is broad with respect to both coupling partners and includes heterocyclic substrates.
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