Journal
ORGANIC LETTERS
Volume 14, Issue 20, Pages 5258-5261Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol302420k
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- Mercator Research Center Ruhr (MERCUR)
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A method for generating (E)-alpha,beta-unsaturated aldehydes from Z-allylic alcohols or E/Z-mixtures is described. The one-pot procedure involves a Cu-catalyzed oxidation followed by an organocatalytic DE-isomerization with N,N-dimethylaminopyridine (DMAP).
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