Journal
ORGANIC LETTERS
Volume 14, Issue 12, Pages 3072-3075Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol3011425
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Funding
- National Science Foundation [CHE-1110911]
- Direct For Mathematical & Physical Scien
- Division Of Chemistry [1110911] Funding Source: National Science Foundation
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The building block synthesis of a derivative of CB[6] that bears a reactive propargyloxy group and its functionalization by click chemistry to yield 1 which contains a covalently attached isobutylammonium group is presented. Compound 1 undergoes self-assembly to yield a cyclic [c2] daisy chain assembly (1(2)) in water. The behavior of 1(2) in response to various stimuli (e.g., guests and CB[n] receptors) is described.
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