Journal
ORGANIC LETTERS
Volume 14, Issue 11, Pages 2746-2749Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol300969g
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Funding
- 973 Program [2011CB-932902]
- NSFC [21172126, 20802038]
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The synthesis of a directly linked zinc chlorin dimer was first achieved by a facile and efficient oxidative coupling of zinc chlorin monomers with phenyliodine bis(trifluoroacetate) (PIFA). The reaction shows high regioselectivity at the 20-position near the hydrogenated pyrrole ring producing selective dichlorin in 74% yield.
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