Journal
ORGANIC LETTERS
Volume 14, Issue 23, Pages 5968-5971Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol302876c
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- Skaggs Institute for Chemical Biology
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The assembly of complex spirocyclopentaneoxindoles via a novel organocatalytic iminium-enamine cascade process is reported. Reactions between 3-substituted oxindoles and alpha,beta-unsaturated aldehydes catalyzed by second generation prolinol ethers provided the desired products in high yield with excellent levels of enantioselectivity in a single step.
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