Journal
ORGANIC LETTERS
Volume 13, Issue 6, Pages 1394-1397Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol2000815
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- University of Geneva
- Swiss NSF
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[CpRu(CH3CN)(3)][PF6] and dilmine ligands catalyze together the decomposition of alpha-diazocarbonyl compounds leading to O-H insertion and condensation reactions. In comparison with Rh(II) and Cu(I) complexes, the CpRu catalysts produce rapid and often more selective reactions. Promising enantioselectivities are obtained in dioxole syntheses.
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