Journal
ORGANIC LETTERS
Volume 13, Issue 7, Pages 1579-1581Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol103156h
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Chiral lithium diphenylbinaphtholate is an effective catalyst for the enantioselective aldol-Tishchenko reaction, affording 1,3-diol derivatives with three contiguous chiral centers and high stereoselectivities. Successive aldol-aldol-Tishchenko reactions gave a triol derivative with five consecutive chiral centers. The present reaction was applicable to highly enantioselective Evans-Tishchenko reduction.
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