Journal
ORGANIC LETTERS
Volume 13, Issue 8, Pages 1908-1911Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol103107v
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- Los Alamos National Laboratory LDRD [ER 20100160]
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Transition metal-catalyzed aerobic alcohol oxidation is an attractive method for the synthesis of carbonyl compounds, but most catalytic systems feature precious metals and require pure oxygen. The vanadium complex (HQ)(2)V(v)(O)(O(I)Pr) (2 mol %, HQ = 8-quinolinate) and NEt(3) (10 mol %) catalyze the oxidation of benzylic, allylic, and propargylic alcohols with air. The catalyst can be easily prepared under air using commercially available reagents and is effective for a wide range of primary and secondary alcohols.
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